Selective methane photooxidation into methanol under mild conditions promoted by highly dispersed Cu atoms on crystalline carbon nitrides.

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dc.contributorCAUE RIBEIRO DE OLIVEIRA, CNPDIA.
dc.creatorSILVA, M. A. R. da
dc.creatorGIL, J. C.
dc.creatorTARAKINA, N. V.
dc.creatorSILVA, G. T. S. T.
dc.creatorFILHO, J. B. G.
dc.creatorKRAMBROCK, K.
dc.creatorANTONIETTI, M.
dc.creatorRIBEIRO, C.
dc.creatorTEIXEIRA, I. F.
dc.date2024-01-23T11:32:55Z
dc.date2024-01-23T11:32:55Z
dc.date2022-12-02
dc.date2022
dc.date.accessioned2026-07-07T04:29:20Z
dc.descriptionHere we report a photocatalytic system based on crystalline carbon nitrides (PHI) and highly dispersed transition metals (Fe, Co and Cu)for controlled methane photooxidation to methanol under mild conditions. The Cu-PHI catalyst showed a remarkable methanol production (2900 lmol g1) in 4 hours, with a turnover number of 51 moles of oxygenated liquid product per mole of Cu. To date, this result is the highest value for methane oxidation under mild conditions (1 bar, 25 8C).
dc.format7419-7422
dc.identifierChemIcal Commununications, vol. 58, 2022.
dc.identifier1364-548X
dc.identifierhttp://www.alice.cnptia.embrapa.br/alice/handle/doc/1149141
dc.identifier10.1039/d2cc01757a
dc.identifier.urihttp://hdl.handle.net/123456789/463005
dc.languageeng
dc.rightsopenAccess
dc.subjectPhotocatalytic system
dc.subjectMethane conversion
dc.titleSelective methane photooxidation into methanol under mild conditions promoted by highly dispersed Cu atoms on crystalline carbon nitrides.
dc.typeArtigo de periódico

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