13CNMR assignments for methyls and quarternary carbons of the limonoid abacunone

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The high field1H and13C resonances of obacunone were established by a series of I D and 2D NMR experiments. The13C-NMR signals of the five tertiary methyl groups and all quatenary carbons were unambiguously assigned. The results confirm the stereochemical assignments at all stereogenic centres.

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fields, methylamines, simaroubaceae, spectroscopy

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